A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand.
نویسندگان
چکیده
The encapsulation of a fluoride ion in a trigonal prismatic CuII6-pyrazolato cage results in a small expansion of the Cu6-host. The structural, electronic and magnetic features of the Cu6-complex, containing an endohedral fluoride in the rare μ6-F coordination mode, are compared with those of the parent complex with a vacant Cu6-cage.
منابع مشابه
Crystal structure of μ6-chlorido-nonakis(μ-4-chloropyrazolato)bis-μ3-methoxo-hexacopper(II)
The hexa-nuclear title compound, [{Cu3(μ3-OCH3)(μ-C3H2ClN2)3}2(μ-C3H2ClN2)3(μ6-Cl)] or [Cu6(C3H2ClN2)9(CH3O)2Cl], crystallizes in the space group Pbcn, with individual mol-ecules being located on a twofold rotation axis. The mol-ecule adopts a trigonal prismatic shape, with two trinuclear units linked by three 4-chloro-pyrazolate ligand bridges by encapsulating a Cl- anion in a μ6-coordination ...
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 47 شماره
صفحات -
تاریخ انتشار 2015